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Synergistic Use of Electrochemical Impedance Spectroscopy and Photoelectrochemical Measurements for Studying Solid State Properties of Anodic HfO2

  • Autori: Santamaria, M; Zaffora, A.; Di Franco, F.; Tranchida, G.; Habazaki, H.; Di Quarto, F.
  • Anno di pubblicazione: 2017
  • Tipologia: Articolo in rivista (Articolo in rivista)
  • OA Link:


Hafnium oxide and Nb doped HfO2 were grown by anodizing sputtering-deposited Hf and Hf-4at.%Nb. Photoelectrochemical characterization was carried out in order to estimate solid state properties such as band gap, flat band potential and electrons internal photoemission threshold energy as a function of thickness and composition of anodic oxides. Impedance measurements were performed in a wide range of electrode potentials in order to study the response of the anodic oxides under anodic and cathodic polarization and to estimate their dielectric constants.