Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks
- Autori: Piscopo, C.; Trapani, F.; Polyzoidis, A.; Schwarzer, M.; Pace, A.; Loebbecke, S.
- Anno di pubblicazione: 2016
- Tipologia: Articolo in rivista (Articolo in rivista)
- OA Link: http://hdl.handle.net/10447/229313
Abstract
Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.