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LEONARDO PALMISANO

N-TiO2 Photocatalysts highly active under visible irradiation for NOX abatement and 2-propanol oxidation

  • Autori: Amadelli, R; Samiolo, L; Borsa, M; Bellardita, M; Palmisano, L
  • Anno di pubblicazione: 2013
  • Tipologia: Articolo in rivista (Articolo in rivista)
  • Parole Chiave: Photocatalysis, N-doped titanium dioxide, Visible light activity, Oxygen vacancies
  • OA Link: http://hdl.handle.net/10447/65451

Abstract

N-doped TiO2 powders were prepared by two different sol–gel methods. Samples were characterised by X-ray diffraction (XRD), BET specific surface area measurements (SSA), scanning electron microscopy (SEM), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and Electron Paramagnetic Resonance (EPR). XPS measurements revealed a signal at 400 eV assignable to nitrogen in the form of Ti N O. EPR signals are attributed to molecular NO trapped with cavities/defects possibly interacting with oxygen vacancies. The photocatalytic activity under UV and visible light was determined following the abatement of NOx and the photodegradation of 2-propanol in gas–solid systems. N-doped TiO2 showed a higher activity compared with the pristine commercial and home prepared samples under visible light irradiation. A good photoactivity in the abatement of both NOx and 2-propanol is also observed for mechanical dispersions of N-TiO2 in CaCO3 serving as a model in view of perspective application in photocatalytically active construction and architectural materials.