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MICHELANGELO GRUTTADAURIA

Oxidative cyclization of aldehyde thiosemicarbazones induced by potassium ferricyanide and by tris(p-bromophenyl)amino hexachloroantimoniate. A joint experimental and computational study

  • Autori: LO MEO, P.; Gruttadauria, M.; Noto, R.
  • Anno di pubblicazione: 2005
  • Tipologia: Articolo in rivista (Articolo in rivista)
  • OA Link: http://hdl.handle.net/10447/19995

Abstract

The oxidative ring closure reaction of some aryl-substituted thiosemicarbazones induced by “bona fide” one-electron abstracting agents was investigated, by means of both experimental and computational techniques. The corresponding 1,2,4-triazole derivatives were the only cyclization products observed. The occurrence of two slightly different mechanistic pathways for the reaction is discussed.