Facile synthesis of ZnO/Hal nanocomposite for arsenite (As(III)) removal from aqueous media

Abstract

Arsenite (As(III)) is the most toxic form of arsenic that is a serious concern for water contamination worldwide. Herein a ZnO/Halloysite (Hal) nanocomposite was prepared by the chemical bath deposition method (CBD) through seed-mediated ZnO growth on the halloysite for eliminating As(III) from the aqueous solution. The growth of ZnO on seeded halloysite was investigated based on the HMTA: Zn2+ molar ratio in the solution. An optimum molar ratio of HMTA:Zn for nucleation and growth of ZnO upon halloysite was obtained 1:2 based on morphological analysis. The TGA results confirmed that thermal stability of HNT was enhanced by ZnO decoration. The prepared ZnO/Hal nanocomposite at optimal conditions was employed for arsenite (As(III)) removal from aqueous solutions. Experimental data were evaluated with different isothermal, thermodynamic, and kinetic models. Based on the zeta potential results, Hal nanocomposites had a greater negative value than pure Hal. Therefore, the ZnO/Hal nanocomposite exhibited efficient As(III) adsorption with a removal efficiency of 76% compared to pure Hal with a removal efficiency of 5%. Adsorption isotherm was well correlated by both non-linear Langmuir and Sips models, exhibiting maximum adsorption capacity of As(III) at 42.07 mg/g, and 42.5 mg/g, respectively. As a result of the study, it was found that the fabricated Hal nanocomposite with low toxicity can be used effectively in water treatment.