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FABRIZIO MESSINA

Structure of the FeBTC Metal–Organic Framework: A Model Based on the Local Environment Study

  • Authors: Sciortino, L; Alessi, A; Messina, F; Buscarino, G; Gelardi, FM;
  • Publication year: 2015
  • Type: Articolo in rivista (Articolo in rivista)
  • Key words: EXAFS
  • OA Link: http://hdl.handle.net/10447/128394

Abstract

The local environment of iron in FeBTC, a metal organic framework commercially known as Basolite F300, is investigated combining XANES and EXAFS studies of the iron K-edge. The building block of the FeBTC can be described as an iron acetate moiety. Dehydration induces a change in the coordination of the first shell while preserving the network. We propose that the local structure around Fe atoms does not undergo a rearrangement, thus, leading to the formation of an open site. The analysis conveys that the FeBTC is a disordered network of locally ordered blocks.