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PELLEGRINO CONTE

Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride

Abstract

—It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple IF that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes.