Synthesis of soluble donor - Acceptor double-cable polymers based on polythiophene and tetracyanoanthraquinodimethane (TCAQ)
- Autori: Giacalone, Francesco; Segura, José L.; MartÃn, Nazario*; Catellani, Marinella; Luzzati, Silvia; Lupsac, Natalia
- Anno di pubblicazione: 2003
- Tipologia: Articolo in rivista (Articolo in rivista)
- Parole Chiave: Anthraquinones; Indicators and Reagents; Luminescent Measurements; Magnetic Resonance Spectroscopy; Polymers; Spectrophotometry, Ultraviolet; Thiophenes; Molecular Medicine
- OA Link: http://hdl.handle.net/10447/286258
Abstract
(Matrix presented) Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.